From: Dynamic combinatorial chemistry at the phospholipid bilayer interface
starting material | pH | T [°C] | k 1 [M-1s-1] | k -1 [M-1s-1] | k h1 [s-1] | k 1 /k -1 | K [a] |
---|---|---|---|---|---|---|---|
1a | 7.0 | 40 | 0.868 × 10-2 ± 1.8 × 10-4 | 3.51 × 10-2 ± 1.3 × 10-3 | 5 × 10-5 ± 2 × 10-5 | 0.25 | 0.29 |
 | 8.0 | 40 | 7.58 × 10-2 ± 6.8 × 10-3 | 18.5 × 10-2 ± 2.3 × 10-2 | 1.1 × 10-4 ± 1 × 10-5 | 0.41 | 0.43 |
 |  | 30 | 2.93 × 10-2 ± 3 × 10-4 | 6.42 × 10-2 ± 1.1 × 10-3 | 6 × 10-5 ± 1 × 10-5 | 0.46 | 0.46 |
 |  | 20 | 1.22 × 10-2 ± 1 × 10-4 | 2.92 × 10-2 ± 4 × 10-4 | 2 × 10-5 1 × 10-5 | 0.42 | 0.44 |
1b | 7.0 | 40 | 1.08 × 10-2 ± 2 × 10-4 | 1.00 × 10-2 ± 8 × 10-4 | 1.64 × 10-3 ± 3 × 10-5 | 1.08 | 1.10 |
 | 8.0 | 40 | 8.13 × 10-2 ± 1.4 × 10-3 | 6.12 × 10-2 ± 2.1 × 10-3 | 2.29 × 10-3 ± 3 × 10-5 | 1.33 | 1.28 |
 |  | 30 | 4.09 × 10-2 ± 1.2 × 10-3 | 4.01 × 10-2 ± 2.1 × 10-3 | 8.0 × 10-4 ± 4 × 10-5 | 1.02 | 1.08 |
 |  | 20 | 1.54 × 10-2 ± 2 × 10-4 | 1.69 × 10-2 ± 6 × 10-4 | 3.2 × 10-4 ± 2 × 10-5 | 0.91 | 0.92 |