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Table 2 Rate constants as defined in Figure 1 for thioester exchange and hydrolysis at the lipid bilayer interface in a DCL made from 13 and 14 at pH 8.0 and 40°C.

From: Dynamic combinatorial chemistry at the phospholipid bilayer interface

starting material k 2 [M-1s-1] k -2 [M-1s-1] k 3 [M-1s-1] k -3 [M-1s-1] k h2 [s-1] k h3 [s-1]
13 1.65 × 10-2
± 0.2 × 10-3
3.31 × 10-2
± 0.8 × 10-3
1.32 × 10-2
± 0.5 × 10-3
5.07 × 10-2
± 2.7 × 10-3
0.008 × 10-2
± 0.9 × 10-5
0.004 × 10-2
± 0.6 × 10-4